Matches in SemOpenAlex for { <https://semopenalex.org/work/W2389479557> ?p ?o ?g. }
Showing items 1 to 63 of
63
with 100 items per page.
- W2389479557 abstract "Tert-butyl 2-cyano-2-(4,6-dimethoxypyrimidin-2-yl) acetate was prepared from 2-chloro-4,6-dimethoxypyrimidine and tert-butyl cyanoacetate.2-(4,6-dimethoxypyrimidin-2-yl) acetonitrile was further synthesized using tert-butyl 2-cyano-2-(4,6-dimethoxypyrimidin-2-yl) acetate as raw material and para-toluenesulfonic acid as catalyst via decarboxylic reaction.Effects of reactant composition,reaction temperature and reaction time on the yield of 2-(4,6-dimethoxypyrimidin-2-yl)acetonitrile were investigated,and the optimal conditions were as follows:molar ratio of n[tert-butyl 2-cyano-2-(4,6-dimethoxypyrimidin-2-yl) acetate]∶n(para-toluenesulfonic acid) was around 1∶0.08,reaction temperature was 100 ℃,and reaction time was 2 hours.The yield of 2-(4,6dimethoxypyrimidin-2-yl)acetonitrile was above 90%.Meanwhile,structure of the product was characterized by IR,1HNMR and 13CNMR methods." @default.
- W2389479557 created "2016-06-24" @default.
- W2389479557 creator A5039136775 @default.
- W2389479557 date "2010-01-01" @default.
- W2389479557 modified "2023-09-24" @default.
- W2389479557 title "Synthesis of 2-(4,6-dimethoxypyrimidin-2-yl) acetonitrile" @default.
- W2389479557 hasPublicationYear "2010" @default.
- W2389479557 type Work @default.
- W2389479557 sameAs 2389479557 @default.
- W2389479557 citedByCount "0" @default.
- W2389479557 crossrefType "journal-article" @default.
- W2389479557 hasAuthorship W2389479557A5039136775 @default.
- W2389479557 hasConcept C134121241 @default.
- W2389479557 hasConcept C13965031 @default.
- W2389479557 hasConcept C155647269 @default.
- W2389479557 hasConcept C161790260 @default.
- W2389479557 hasConcept C178790620 @default.
- W2389479557 hasConcept C185592680 @default.
- W2389479557 hasConcept C191897082 @default.
- W2389479557 hasConcept C192562407 @default.
- W2389479557 hasConcept C2777463227 @default.
- W2389479557 hasConcept C2778341971 @default.
- W2389479557 hasConcept C2991944050 @default.
- W2389479557 hasConcept C2994067411 @default.
- W2389479557 hasConceptScore W2389479557C134121241 @default.
- W2389479557 hasConceptScore W2389479557C13965031 @default.
- W2389479557 hasConceptScore W2389479557C155647269 @default.
- W2389479557 hasConceptScore W2389479557C161790260 @default.
- W2389479557 hasConceptScore W2389479557C178790620 @default.
- W2389479557 hasConceptScore W2389479557C185592680 @default.
- W2389479557 hasConceptScore W2389479557C191897082 @default.
- W2389479557 hasConceptScore W2389479557C192562407 @default.
- W2389479557 hasConceptScore W2389479557C2777463227 @default.
- W2389479557 hasConceptScore W2389479557C2778341971 @default.
- W2389479557 hasConceptScore W2389479557C2991944050 @default.
- W2389479557 hasConceptScore W2389479557C2994067411 @default.
- W2389479557 hasLocation W23894795571 @default.
- W2389479557 hasOpenAccess W2389479557 @default.
- W2389479557 hasPrimaryLocation W23894795571 @default.
- W2389479557 hasRelatedWork W2002950116 @default.
- W2389479557 hasRelatedWork W2348487987 @default.
- W2389479557 hasRelatedWork W2348986037 @default.
- W2389479557 hasRelatedWork W2349065407 @default.
- W2389479557 hasRelatedWork W2350600401 @default.
- W2389479557 hasRelatedWork W2360431930 @default.
- W2389479557 hasRelatedWork W2361033462 @default.
- W2389479557 hasRelatedWork W2364606483 @default.
- W2389479557 hasRelatedWork W2368907405 @default.
- W2389479557 hasRelatedWork W2371585620 @default.
- W2389479557 hasRelatedWork W2376499819 @default.
- W2389479557 hasRelatedWork W2377162445 @default.
- W2389479557 hasRelatedWork W2378481068 @default.
- W2389479557 hasRelatedWork W2379739067 @default.
- W2389479557 hasRelatedWork W2383585523 @default.
- W2389479557 hasRelatedWork W2383655710 @default.
- W2389479557 hasRelatedWork W2390730167 @default.
- W2389479557 hasRelatedWork W2870682616 @default.
- W2389479557 hasRelatedWork W2967070948 @default.
- W2389479557 hasRelatedWork W3034073397 @default.
- W2389479557 isParatext "false" @default.
- W2389479557 isRetracted "false" @default.
- W2389479557 magId "2389479557" @default.
- W2389479557 workType "article" @default.