Matches in SemOpenAlex for { <https://semopenalex.org/work/W2389596035> ?p ?o ?g. }
- W2389596035 endingPage "5558" @default.
- W2389596035 startingPage "5547" @default.
- W2389596035 abstract "Indeno[1,2-b]fluorenes (IFs), while containing 4n π-electrons, are best described as two aromatic benzene rings fused to a weakly paratropic s-indacene core. In this study, we find that replacement of the outer benzene rings of an IF with benzothiophenes allows the antiaromaticity of the central s-indacene to strongly reassert itself. Herein we report a combined synthetic, computational, structural, and materials study of anti- and syn-indacenodibenzothiophenes (IDBTs). We have developed an efficient and scalable synthesis for preparation of a series of aryl- and ethynyl-substituted IDBTs. NICS-XY scans and ACID calculations reveal an increasingly antiaromatic core from [1,2-b]IF to anti-IDBT, with syn-IDBT being nearly as antiaromatic as the parent s-indacene. As an initial evaluation, the intermolecular electronic couplings and electronic band structure of a diethynyl anti-IDBT derivative reveal the potential for hole and / or electron transport. OFETs constructed using this molecule show the highest hole mobilities yet achieved for a fully conjugated IF derivative." @default.
- W2389596035 created "2016-06-24" @default.
- W2389596035 creator A5001681291 @default.
- W2389596035 creator A5012431807 @default.
- W2389596035 creator A5023912907 @default.
- W2389596035 creator A5031639651 @default.
- W2389596035 creator A5034244442 @default.
- W2389596035 creator A5035359720 @default.
- W2389596035 creator A5049912304 @default.
- W2389596035 creator A5056847387 @default.
- W2389596035 creator A5062961446 @default.
- W2389596035 creator A5077199989 @default.
- W2389596035 creator A5079258753 @default.
- W2389596035 creator A5082681305 @default.
- W2389596035 creator A5084999737 @default.
- W2389596035 date "2016-01-01" @default.
- W2389596035 modified "2023-10-17" @default.
- W2389596035 title "Indacenodibenzothiophenes: synthesis, optoelectronic properties and materials applications of molecules with strong antiaromatic character" @default.
- W2389596035 cites W1255158138 @default.
- W2389596035 cites W1274277762 @default.
- W2389596035 cites W1518880490 @default.
- W2389596035 cites W1524660474 @default.
- W2389596035 cites W1779668928 @default.
- W2389596035 cites W1881548054 @default.
- W2389596035 cites W1935454572 @default.
- W2389596035 cites W1970152444 @default.
- W2389596035 cites W1976849993 @default.
- W2389596035 cites W1977993211 @default.
- W2389596035 cites W1979270591 @default.
- W2389596035 cites W1979815143 @default.
- W2389596035 cites W1980530818 @default.
- W2389596035 cites W1983196479 @default.
- W2389596035 cites W1984284109 @default.
- W2389596035 cites W1984376306 @default.
- W2389596035 cites W1984635750 @default.
- W2389596035 cites W1991119497 @default.
- W2389596035 cites W1992046881 @default.
- W2389596035 cites W1993365580 @default.
- W2389596035 cites W1996217107 @default.
- W2389596035 cites W2002645636 @default.
- W2389596035 cites W2003495579 @default.
- W2389596035 cites W2003516675 @default.
- W2389596035 cites W2004982819 @default.
- W2389596035 cites W2010047027 @default.
- W2389596035 cites W2014107908 @default.
- W2389596035 cites W2015106953 @default.
- W2389596035 cites W2015623387 @default.
- W2389596035 cites W2020400781 @default.
- W2389596035 cites W2022914117 @default.
- W2389596035 cites W2024424555 @default.
- W2389596035 cites W2025044141 @default.
- W2389596035 cites W2029966637 @default.
- W2389596035 cites W2032003798 @default.
- W2389596035 cites W2032719166 @default.
- W2389596035 cites W2036578811 @default.
- W2389596035 cites W2036646032 @default.
- W2389596035 cites W2045490264 @default.
- W2389596035 cites W2048520886 @default.
- W2389596035 cites W2048535684 @default.
- W2389596035 cites W2049492846 @default.
- W2389596035 cites W2050179690 @default.
- W2389596035 cites W2050791206 @default.
- W2389596035 cites W2053248916 @default.
- W2389596035 cites W2054164390 @default.
- W2389596035 cites W2055601983 @default.
- W2389596035 cites W2056881087 @default.
- W2389596035 cites W2058957873 @default.
- W2389596035 cites W2059197962 @default.
- W2389596035 cites W2059668887 @default.
- W2389596035 cites W2061111213 @default.
- W2389596035 cites W2062662415 @default.
- W2389596035 cites W2063529487 @default.
- W2389596035 cites W2064496332 @default.
- W2389596035 cites W2064751819 @default.
- W2389596035 cites W2067263051 @default.
- W2389596035 cites W2067570011 @default.
- W2389596035 cites W2069305075 @default.
- W2389596035 cites W2072004503 @default.
- W2389596035 cites W2080051857 @default.
- W2389596035 cites W2086209969 @default.
- W2389596035 cites W2086428976 @default.
- W2389596035 cites W2086911521 @default.
- W2389596035 cites W2091720348 @default.
- W2389596035 cites W2093849085 @default.
- W2389596035 cites W2095292871 @default.
- W2389596035 cites W2096785312 @default.
- W2389596035 cites W2100606224 @default.
- W2389596035 cites W2103561834 @default.
- W2389596035 cites W2109958925 @default.
- W2389596035 cites W2113957585 @default.
- W2389596035 cites W2114344620 @default.
- W2389596035 cites W2118011826 @default.
- W2389596035 cites W2118946568 @default.
- W2389596035 cites W2120059112 @default.
- W2389596035 cites W2121170859 @default.
- W2389596035 cites W2122638133 @default.
- W2389596035 cites W2124032955 @default.
- W2389596035 cites W2125817749 @default.