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- W2389687560 abstract "The in situ prepared chiral catalyst of Pd/unchelating bidentate phosphine ligand L1(DPPFF),bipyridine bidentate phosphine ligand L2(P-PHOS),and bidentate phosphine ligand L3((S,Rp)-BPPF),and Rh/phosphite ligands L4-L6,have been applied in amidocarbonylation of cyclohexanecarboxaldehyde or phenylacetaldehyde.Pd/bipyridine bidentate phosphine ligand L2 gave the enantioselectivity 25%(S) and the yield 11% in amidocarbonylation of phenylacetaldehyde,When Pd/unchelating bidentate phosphine ligand L1 was employed in asymmetric amidocarbonylation of cyclohexanecarboxaldehyde,the enantioselectivity 4.3%(S) and the yield 15% were received." @default.
- W2389687560 created "2016-06-24" @default.
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- W2389687560 date "2011-01-01" @default.
- W2389687560 modified "2023-09-25" @default.
- W2389687560 title "Asymmetric Amidocarbonylation of Aldehyde and Acetamide Catalyzed by Chiral Palladium or Rhodium Complexes" @default.
- W2389687560 hasPublicationYear "2011" @default.
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