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- W2390375375 abstract "Artificial receptors that are capable of selectively binding anionic species show promise in the diagnosis and treatment of diseases,and in environmental remediation. Several anion receptors have been constructed from five-membered heterocycles,such as imidazole. In this article,an imidazolium branched zinc porphyrin was designed and synthesized as chemosensor because the electronic spectra of porphyrin were very sensitive to the change of the environment. The UV-Vis,fluorescence and 1H NMR studies revealed that this receptor could selectively bind F-and Cl-over other halide anions. After comparing with the imidazolium branched freebase porphyrin,the model of the anionic binding was considered as three-point cooperation with haloid anions through porphyrin core and two imidazole moieties." @default.
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- W2390375375 date "2009-01-01" @default.
- W2390375375 modified "2023-09-25" @default.
- W2390375375 title "Synthesis of a Novel Bisimidazolium Branched Zinc Metalloporphyrin and Its Recognition for Halide Anion" @default.
- W2390375375 hasPublicationYear "2009" @default.
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