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- W2390428711 abstract "Initiation mechanism of the photopolymerization of acrylonitrile and methyl methacrylate, usingbinary condensed aromatic hydrocarbon (CAH)-aniline systems as initiator, was studied. The strongerthe electron-donating ability of the aniline derivatives, the faster the the of photopolymerizationwill be. The radical intermediates produced by photoreaction between anthracene and anilinewere detected with ESR spectra. The initiation scheme involves the formation of exciplex betweenthe excited singlet state of CAH and the ground state of aniline as the first step, and then followedby proton transfer, leading to the generation of two kinds of radicals. From the end-group analysisof the polymers obtained, it is suggested that both kinds of radicals are involved in the initiation." @default.
- W2390428711 created "2016-06-24" @default.
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- W2390428711 date "1985-01-01" @default.
- W2390428711 modified "2023-09-23" @default.
- W2390428711 title "STUDIES ON THE MECHANISM OF VINYL PHOTOPOLYMERIZATION INITIATED BY CONDENSED AROMATIC HYDROCARBON-ANILINE SYSTEMS" @default.
- W2390428711 hasPublicationYear "1985" @default.
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