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- W2390859518 abstract "Stilbazium iodic (symboled as S) has high BBBBBBBB value and has been used to prepare-LB films, but the deposition properties of S and the stabilities of S-LB films are very poor. The mixed systems of stilbazium salt and cadmium arachidate (symboled aa SA, the molecular ratio RM = S/A = 0 to 1)can improve the deposition property, but. the stability of SA-LB films are still poor. The present work is to investigate the microstructure and superstructure of S-LB and SA-LB films, and the reason of unstability of these films by SAXS and MOMI. The results are as follows. First, the fatty chains of both stilbazium salt and cadmium arachi date can form thecrystal-like structure of two-dimension as same as the usual fatty acid. Second, the phase-inversion of S and A from dispersed phase to continuous phase occurs as RM changes from 0 to 1. Third, in the crystal-like of two-dimension S-molecules are in high energy and full-straighten conformation, but the stilbazium group of dumbbell-shape tends to pile up in the oblique and close packingform; two fatty chains of S tend to extend in the lower energy trans-form and swallowtail conformation; the lengh of the fatty chains (C16) is about 2/3 lengh of S-molecule, so the molecular forces between SSor S-AS are less than that of usual fatty acid and Y-type LB films of S continuous phase are unstable. Fourth, a lot of lattice defect exist in two-dimension crystal-like of SA-systems as mentioned above, so only 4 to 6 layers unstable and less regular Y-type SA-LB films could be prepared and these layers' structure collapse after 1. month" @default.
- W2390859518 created "2016-06-24" @default.
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- W2390859518 date "1994-01-01" @default.
- W2390859518 modified "2023-09-26" @default.
- W2390859518 title "Studies of SAXS on the Microstructure and Superstructure of Finite-Layer Langmuir-Blodgett Crystal-Like Films II. The Mixed Film Systems of Stilbazium Salt and Cadmium Arachidate" @default.
- W2390859518 hasPublicationYear "1994" @default.
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