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- W2391310448 abstract "Two compounds of antimony trichloride and bismuth trichloride with valine are synthesized by solid phase synthesis at room temperature.Their compositions,determined by element analysis,are Sb(C5H10O2N)3·2H2O and Bi(C5H10O2N)2Cl·0.5H2O.The crystal structure of antimony complex with valine belongs to triclinic system and its lattice parameters are: a= 0.959 9 nm,b=1.506 8 nm,c=1.985 1 nm,α=92.27°,β=95.05°,γ=104.27°.The crystal structure of bismuth complex with valine belongs to monoclinic system and its lattice parameters are: a=1.601 2 nm,b=1.894 1 nm,c=1.839 nm,β=99.73°.The far-infrared spectra and the infrared spectra show that the amino group and carboxyl of valine may be coordinated to antimony and bismuth,respectively,in two compounds.The TG-DSC results also reveal that the complexes are formed." @default.
- W2391310448 created "2016-06-24" @default.
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- W2391310448 date "2011-01-01" @default.
- W2391310448 modified "2023-09-23" @default.
- W2391310448 title "Preparation and Structure Analysis of Antimony Trichloride and Bismuth Trichloride Comlexes with Valine" @default.
- W2391310448 hasPublicationYear "2011" @default.
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