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- W2391457584 abstract "The inclusion interaction of perhydroxycucurbit[6]uril(HOCB6)with Tb(III) by fluorimetric methods.The results indicate that the ion-dipole and complex interactions resulted in the formation of 1:1 type inclusion complex HOCB6-Tb(III).The complex constant was determined to be 5.40×10~4 Lmol~(-1).The effect of the acid concentration on the fluorescent intensity and the stability of the complex were investigated.The comparative study of Tb(III) with other supramolecules,such as cucurbit[6]uril,β-cyclodextrin and p-(N,N-dimethylamino-methyl)-calix[8]arene,was also carried out.The spectra changes show that cucurbit[6]uril and p-(N,N-dimethyl-aminomethyl)-calix[8]arene with Tb(III) can also form stable 1:1 type complexes,instead of β-cyclodextrin.The complex constants of cucurbit[6]uril and p-(N,N-dimethyl-aminomethyl)-calix[8]arene with Tb(III) were 5.84×10~2 Lmol~(-1) and 1.87×10~4 Lmol~(-1) respectively,which were related to the sizes of cavities and the inclusion abilities of host supramolecules." @default.
- W2391457584 created "2016-06-24" @default.
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- W2391457584 date "2006-01-01" @default.
- W2391457584 modified "2023-09-25" @default.
- W2391457584 title "Study on the Inclusion Interaction of Perhydroxycucurbit[6] uril with Tb(III) by Fluorimetric Method" @default.
- W2391457584 hasPublicationYear "2006" @default.
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