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- W2391544107 abstract "An intelligent data base of the phase diagrams of molten salt systems has been built in our laboratory.It includes more than 3000 known phase diagrams of binary and ternary molten salt systems for retrieval.In the course of building of this data base,atomic parameter-pattern recognition method has been used to extract the semi-empirical rules about the relationships between the geometrical features of phase diagrams and the atomic parameters(ionic radius and electronegativity)of the constituent elements of salts.Based on these semi-empirical rules found,the geometrical features of unknown phase diagrams can be predicted.Besides,some published phase diagrams are found to be the exceptions(outliers)of these semiempirical rules can be considered to be suspectable and should be re-measured by experimental work.By this way,a series of published phase diagrams has been correted in our laboratory.Some phase diagrams have been found to include more intermediate compounds,such as CsCaBr 3 and Cs 2CaF 4;while some intermediate compounds in KNO 3-Kl,KNO 3-KBr,KNO 3-KCl systems claimed by some authors have been disproved in our work.So it is reasonable to consider that atomic parameter-pattern recognition method together with experimental re-determination is an effective way for the assessment of phase diagrams." @default.
- W2391544107 created "2016-06-24" @default.
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- W2391544107 date "2003-01-01" @default.
- W2391544107 modified "2023-09-24" @default.
- W2391544107 title "Intelligent Data Base of Phase Diagrams of Molten Salt Systems" @default.
- W2391544107 hasPublicationYear "2003" @default.
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