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- W2391584848 abstract "The dinuclear copper(Ⅱ) macrocyclic complex has been synthesized by condensation between N,N′-dimethyl-N,N′-bis(3-formyl-5-chlorosalicylidene)ethylene diamine and 1,3-propanediamine in the presence of copper(Ⅱ)? The complex was determined by X-ray diffractions single crystal structure analysis.The results indicates that the complex crystallizes in monoclinic,space group P21,Flack parameters(x) =0.06(2),with a=0.871 05(16) nm,b=0.957 78(18) nm,c=1.810 4(3) nm,β=100.761(18)°,V=1.483 8(5) nm3,Z=2,Dc=1.762 Mg·m-3,μ=1.85 mm-1,F(000)=796,and final R1=0.061,wR2=0.126,The crystal structure shows that the two copper(Ⅱ) ions in the phenol-based macrocyclic dinuclear complex,are coordinated with(Namine)2O2 and(Nimine)2O2 sites.Magnetic measurements reveal an antiferromagentic interaction in the complex.CCDC: 624712." @default.
- W2391584848 created "2016-06-24" @default.
- W2391584848 creator A5088314105 @default.
- W2391584848 date "2011-01-01" @default.
- W2391584848 modified "2023-09-25" @default.
- W2391584848 title "Synthesis,Crystal Structure and Magnetic Properties of the Asymmetric Dinuclear Copper(II) Macrocyclic Complex [Cu_2(C_(23)H_(26)Cl_2N_4O_2)](ClO_4)_2" @default.
- W2391584848 hasPublicationYear "2011" @default.
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