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- W2391612084 abstract "Organic film photovoltaic cell, ITO/TPD/Gd(DBM)3bath/Mg∶Ag, was fabr icated. The TPD, N,N'diphenylN,N'bis(3methylphenyl)1,1'diphenyl4,4' diami ne, and Gd(DBM)3bath, gadolinium (dibenzoylmethanato)3(bathophenanthroline) , ar e the electron acceptor and donor, respectively. Fabrication process is indicate d shortly. Although TPD acts as an active layer in the bilayered cells, insertio n of a Gdcomplex film between TPD and the alloy cathode is necessary for effic i ent carrier photogeneration. Under the irradiation of 365nm UV light wi th 4mW/cm2, t he cell shows shortcircuit current of 2924μA/cm2, opencircuit voltage o f 3. 2V, fill factor of 0.286 and external quantum efficiency of 273, respectivel y. And the spectral response region of EQE is matched to the absorption spectrum o f TPD film, suggesting t hat it's the absorption of TPD layer but not that of the Gd(DBM)3 bath plays a d ominant role in the creation of photovoltaic. We also demonstrated the rela tions hip between photovoltaic phenomena and exciplex, *, which generated at the interface between TPD and Gd(DBM)3 bath layers. And we ca n say t hat in the photovoltaic progress the exciplex * a ct s as a holeelectron pair, or in other words, acts as lightgenerated exciton." @default.
- W2391612084 created "2016-06-24" @default.
- W2391612084 creator A5011407484 @default.
- W2391612084 date "2003-01-01" @default.
- W2391612084 modified "2023-09-23" @default.
- W2391612084 title "Organic Film Photovoltaic Cell with Rear-earth Complex" @default.
- W2391612084 hasPublicationYear "2003" @default.
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