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- W2391744323 abstract "A simulated oil consisting of thiophene as model sulfur compounds and as solvent was employed for the oxidative extraction desulfurization in catalytic oxidative system of Ti-MCM-41/H2O2·HCOOH. By using orthogonal design,the optimal reaction time,temperature,amount of H2O2 and all significant factors affecting the desulfurization of simulated oil containing thiophene were obtained,including the H2O2 addition volume fraction of 1%,the reaction temperature of 50℃ and the time of 40 min,under which the removal ratio of thiophene was 95.6% and gasoline yield was 98.7%. The influences of dosage and reuse times of Ti-MCM-41 on removal ratio of thiophene were also investigated. From the kinetics study,it indicated that the reaction was a pseudo first-order reaction,and the activation energy Ea is 40.18 kJ/mol." @default.
- W2391744323 created "2016-06-24" @default.
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- W2391744323 date "2009-01-01" @default.
- W2391744323 modified "2023-09-23" @default.
- W2391744323 title "SELECTIVE OXIDATION AND KINETICS OF Ti-MCM-41/H_2O_2·HCOOH SYSTEM FOR THIOPHENE IN SIMULATED GASOLINE" @default.
- W2391744323 hasPublicationYear "2009" @default.
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