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- W2391785197 abstract "Indium,tin and bismuth nanoparticles successfully mediated crotylation of carbonyl compounds in water to afford the corresponding homoallylic alcohols with good to excellent yields in a short time.The reactivity, regioselectivity and diastereoselectivity of crotylation reaction could be adjusted by different metal nanoparticles.The crotylations promoted by indium nanoparticles produced the exclusive γ-adducts with major anti-isomers.Tin nanoparticle-mediated crotylation afforded the major γ-adducts with dominant anti-isomers while bismuth nanoparticle-mediated crotylation produced the major γ-adducts with dominant syn-isomers.The proposed mechanism for the crotylation was discussed." @default.
- W2391785197 created "2016-06-24" @default.
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- W2391785197 date "2008-01-01" @default.
- W2391785197 modified "2023-09-24" @default.
- W2391785197 title "Crotylation of carbonyl compounds with crotyl bromide mediated by different metal nanoparticles in water" @default.
- W2391785197 hasPublicationYear "2008" @default.
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