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- W2391995423 abstract "The FeCl_3 graphite intercalation compounds (FeCl_3-GICs) have aroused special attention for their highly electrical conductivity and stability. In this paper, FeCl_3-exfoliated graphite intercalation compounds (Abs. FeCl_3-EGICs) have been synthesized under the protection of nitrogen gas with the melting salt method. The experimental results show that pure stage-I FeCl_3-EGICs can be synthesized at 360℃ for 12 hours, and pure stage-II FeCls3-EGICs at 460℃ for 12 hours when FeCl_3 is excessive. In addition, the electrical conductivity of FeCl_3-EGICs was measured at different temperatures, the number of stage Ⅰ EGICs is 7.513×106S·m -1 at 297K which is 3.7 times larger than pristine exfoliated graphite, and stage Ⅱ is 6.87×106 S·m -1 at the same temperature which is 3.4 times larger. The conductance of FeCl_3-EGICs is similar to that of metals, and its electrical resistivity shows a linear relation with the temperature from 297K to decomposition temperature. The resistivity increases with temperature, with the mechanism being phonon scattering." @default.
- W2391995423 created "2016-06-24" @default.
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- W2391995423 date "2005-01-01" @default.
- W2391995423 modified "2023-09-26" @default.
- W2391995423 title "Synthesis and electrical conductivity of FeCl_3 exfoliated graphite intercalation compounds" @default.
- W2391995423 hasPublicationYear "2005" @default.
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