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- W2392041036 abstract "Trifluoromethane(CF3H,HFC-23) is used commonly now in fire extinguishing agent market.However,when CF3H is discharged into the fire protection area,HF will be produced by the interaction between the flame and CF3H.HF not only has severe erosion to the apparatus,but also makes serious harm to the people in fire scene.In this paper,the decomposition process and the fire extinguishing mechanism of CF3H were calculated by ab initio method at B3LYP/6-311++G(d,p) level and the model for predicting HF productive amount was proposed.And then,by in-situ spectral diagnostics method,the concentration of HF was measured real-timely when CF3H was discharged into cup-burner to extinguish alcohol fire.Finally,by comparing the theoretical prediction results with experimental results,the reliability of HF production predicting model was proved.The studies in this paper not only deepen the understand for the HF productive mechanism,but also gave a strong support for the decrease of HF productive amount and instruct the optimization of CH3H fire extinguishing system designation." @default.
- W2392041036 created "2016-06-24" @default.
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- W2392041036 date "2011-01-01" @default.
- W2392041036 modified "2023-09-25" @default.
- W2392041036 title "Amount and Mechanism of HF Production in Fire Extinguishing Process Using CF_3H" @default.
- W2392041036 hasPublicationYear "2011" @default.
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