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- W239227104 abstract "The product of the reaction of (tBu2PCH2SiMe2)2N− (MgCl+ salt) with [RhCl(cyclooctene)2]2 is a RhIII complex where one tBu methyl C−H bond has oxidatively added to Rh: (PNP*)RhH. This is in rapid exchange among all 9 × 4 C−H bonds of the four tBu groups. (PNP*)RhH undergoes oxidative addition equilibrium with the C−H bonds of benzene at ∼103 s−1 at 25 °C and oxidatively adds the ring C−H of other arenes. (PNP*)RhH forms η2-olefin complexes with several olefins and dehydrogenates allylic C−H bonds to form (PNP)Rh(H)2." @default.
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- W239227104 date "2007-12-29" @default.
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- W239227104 title "[(<sup>t</sup>Bu<sub>2</sub>PCH<sub>2</sub>SiMe<sub>2</sub>)<sub>2</sub>N]Rh<sup>I</sup>? Rapidly Reversible H−C(sp<sup>3</sup>) and H−C(sp<sup>2</sup>) Bond Cleavage by Rhodium(I)" @default.
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- W239227104 doi "https://doi.org/10.1021/om701165n" @default.
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