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- W2392493844 abstract "Two series of alkali salts of bis(polyfluoroalkyloxysulfonyl) imides,alkali bis(2,2,2-trifluoroethoxysulfonyl) imides{ M[N(SO2OCH2CF3)2],MTFESI} and alkali bis[(1,1,1,3,3,3-hexafluoro-2-propoxy) sulfonyl]imides(M{ N[SO2OCH(CF3)2]2},MHFPSI)(M = Li,Na,K,Rb,Cs),were prepared and characterized by NMR,IR and elemental analysis. Thermal properties of the neat salts were investigated by differential scanning calorimetry(DSC) and thermogravimetric analysis(TGA). The fundamental physicochemical properties of nonaqueous electrolytes of lithium bis(polyfluoroalkyloxysulfonyl) imides are studied. The results indicate that the alkali bis(polyfluoroalkyloxysulfonyl) imides show high thermal stability and low melting point. The electrolytes of 1. 0 mol/L lithium salt in a mixture of ethylene carbonate(EC)/ethyl methyl carbonate(EMC)(3 ∶ 7,volume ratio) show medium conductivities,high oxidation potentials and do not corrode Al in the high potential region of 3—5 V(vs. Li+/Li)." @default.
- W2392493844 created "2016-06-24" @default.
- W2392493844 creator A5031235937 @default.
- W2392493844 date "2014-01-01" @default.
- W2392493844 modified "2023-09-24" @default.
- W2392493844 title "Preparation,Characterization and Physicochemical Properties of Alkali Bis(polyfluoroalkyloxysulfonyl) imides and Electrochemical Properties of the Lithium Salts" @default.
- W2392493844 hasPublicationYear "2014" @default.
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