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- W2392610316 abstract "To explore the effects of the substituted groups and heterocyclic types of the ligands on the reaction equilibrium,the interactions between diperoxovanadate complex NH4[OV(O2)2(picolinamide)]·H2O(Abbr.bpV(picamd)) and a series of zole-like ligands in solution were explored using multinuclear(1H,13C,and 51V) magnetic resonance in 0.15 mol/L NaCl ionic medium for mimicking the physiological condition.The reactivity among these orgnic ligands and bpV(picamd) were imidazole 2-methylimidazole pyrazole ≈ 3-methyl-pyrazole.The experimental results indicated that the coordinating ability of imidazole-like ligands is stronger than that of pyrazole-like ligands.The substituted groups in 2-position affected the reaction equilibrium for the imidazole-like ligands;However,the 3-substituted pyrazole has almost the same coordinating ability as the pyrazole.The competitive coordination results in the formation of a series of new six-coordinated peroxovanadate species [OV(O2)2L]-(L = zole-like ligands)." @default.
- W2392610316 created "2016-06-24" @default.
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- W2392610316 date "2010-01-01" @default.
- W2392610316 modified "2023-09-25" @default.
- W2392610316 title "NMR studies on interactions between diperoxovanadate complex and zole-like ligands" @default.
- W2392610316 hasPublicationYear "2010" @default.
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