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- W2392708546 abstract "Selective oxidation of benzoic alcohol to benzaldehyde with 30% hydrogen peroxide,catalyzed by Na2WO4·2H2O in acidic ionic liquid[(CH2)4SO3HMIm]TSO in the absence of organic solvents and halide,was studied.Optimal results was obtained with benzoic alcohol conversion of 90.1% and selectivity to benzaldehyde of 92.1% under condition as follows: at 90 ℃ for 3 h,n(benzyl alcohol)∶n(H2O2)∶n(ionic liquids)∶n(Na2WO4·2H2O)=40∶48∶1∶1.Benzaldehyde product was immiscible with acidic ionic liquid and easily separated from the ionic liquid.The ionic liquid could be repeatedly used for four times after vacuum drying without considerable loss of activity." @default.
- W2392708546 created "2016-06-24" @default.
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- W2392708546 date "2007-01-01" @default.
- W2392708546 modified "2023-09-25" @default.
- W2392708546 title "Catalytic oxidation of benzoic alcohol to benzaldehyde in acidic ionic liquid" @default.
- W2392708546 hasPublicationYear "2007" @default.
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