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- W2392823368 abstract "Nucleophilic addition is a characteristic reaction of a buckminsterfullerene.However,the addition of nucleophiles to C60,in most cases leads to a myriad of different polyadducts which are difficult to separate into isomerically pure compounds.The addition of NaCN to C60 revealed that the controllable mono-adduction of CN to C60 was obtained,which produced only C60(CN)-,using the mixture of DMF and 1,2-dichlorobenzene(ODCB) as the solvent.Without separation,protonation of C60(CN)-with trifluoroacetic acid produced C60(CN)H as the single isomer.When C60(CN)-was treated with tosyl cyanide at room temperature,the C60(CN)2 was formed,as a single isomer,in high yield.The products were characterized by 1H NMR,ESI-MS and elemental analysis." @default.
- W2392823368 created "2016-06-24" @default.
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- W2392823368 date "2010-01-01" @default.
- W2392823368 modified "2023-09-27" @default.
- W2392823368 title "The Synthesis and Characterization of Cyanofullerene and 1,2-Dicyanofulleren" @default.
- W2392823368 hasPublicationYear "2010" @default.
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