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- W2393039705 abstract "The curing process of dendritic polymer PAMAM with bis-phenol A epoxy resin was investigated using isothermal differential scanning calorimetry(DSC),the mechanism of this reaction was autocatalytic.The data of two reaction rate constants k_1,k_2 and reaction orders m,n were obtained from Kamal equation.The overall reaction order m+n was between 2.07 and 2.29,the apparent activation energies of E_1 and E_2 were 59.79 kJ/mol and 56.51 kJ/mol, respectively.The reaction entered into a diffusion controlled stage at the conversion of 50%,experimental data and theoretic curve had deviation at this time.The reaction conversion,at which the deviation occurred,decreased with lowering curing temperature." @default.
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- W2393039705 date "2006-01-01" @default.
- W2393039705 modified "2023-09-24" @default.
- W2393039705 title "STUDIES ON CURING KINETICS OF DENDRITIC POLYMER PAMAM WITH EPOXY RESIN BY ISOTHERMAL DSC" @default.
- W2393039705 hasPublicationYear "2006" @default.
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