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- W2393262495 abstract "MS characteristics of monosulfuron-ester were analysized by comparison between reversed-phase HPLC/ESI/MS and HPLC/APCI/MS. Monosulfuron-ester gave positive-ion ESI/MS spectra with major [M+H]+ and [M+Na]+,[2M+Na]+,[2M+K]+ ion and negative-ion ESI-MS spectra with dominant [M-H]-and [2M-2H+Na]-ions. Fragments and structurally informative spectra such as [M+H]+,[M-H]-and m/z of 110.31,136.24,168.18,244.19 were found in APCI/MS with [M+H]+ ion in positive-ion mode as predominant and [M-H]-ion in negative-ion mode as preferential.Accordingly,negative-ion of ESI/MS and APCI/MS could be utilized to identify monosulfuron ester by its molecular ions; whereas positive-ion of APCI/MS could be used for its identification study by the succeeding cleavage of the specific ions in multi MS/MS environment." @default.
- W2393262495 created "2016-06-24" @default.
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- W2393262495 date "2009-01-01" @default.
- W2393262495 modified "2023-09-26" @default.
- W2393262495 title "Study on the Analysis of Monosulfuron-ester by HPLC/MS/MS" @default.
- W2393262495 hasPublicationYear "2009" @default.
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