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- W2393276279 abstract "Reaction mechanism of synthesizing oxalic acid by starch and nitric acid with catalyst and cocatalyst under acidic condition is explored. The macroscopical dynamics mode of starch becoming glucose by hydrolysis under acidic condition, the glucose further becoming oxalic acid by nitric acid oxidation is put forward. This course divides into two steps: starch hydrolysis course is apparent first order reaction, the dynamics equation is: CA=CA0exp(-k1t); the glucose oxidation course is handled by steady state method, the dynamics equation is: CE=CB0(1-e-k2t). Through experiment, it can be obtained by parameter calculation that k1 = 0.082min-1, k2 = 0.0050min-1. The research results provide theoretical and technical support for the recycling utilization of the red fuming nitric acid as discard liquid propellant." @default.
- W2393276279 created "2016-06-24" @default.
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- W2393276279 date "2008-01-01" @default.
- W2393276279 modified "2023-09-26" @default.
- W2393276279 title "Study on Kinetics of Oxalic Acid Preparation by Starch Oxidized With Nitric Acid" @default.
- W2393276279 hasPublicationYear "2008" @default.
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