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- W2393338417 abstract "The molecular weight distribution by sedimentation velocity measurements and hydrostatic pressure correction for the sedimentation coefficient of the floating system poly-dimethylsiloxane-bromocyclohexane at θ-temperature (28 ℃) have been studied. A new method for the experimental evaluation of the hydrostatic pressure correction of the sedimentation coefficient is proposed. By using different quantities of the solution added to the sedimentation cell, so as to give different heights of the liquid column, it is possible to determine the influence of the hydrostatic pressure on the sedimentation coefficient. Assuming a linear relation between the sedimentation coefficient and the hydrostatic pressure, the authors found that the pressure coefficient of the system studied is 1.44×10-3 (atm)-1 for hydrostatic pressures less than 200 atm.From the distribution of sedimentation coefficients, and the values of Mw, [η]θ, and [η] toluene of a polydimethylsiloxane fraction the monodisperse relationships s-M, [η]θ-M, in the θ-solvent at 28℃ and [η]tolucne-M at 25℃ are obtained:s1 = 6.30 × 10-16M0.50 (bromocyclohexane, 28℃) [η]θ = 7.41 × 10-2 M0.50 (bromocyclohexane, 28℃) [η] = 9.53 × 10-3 M0.71 (toluene, 25℃)" @default.
- W2393338417 created "2016-06-24" @default.
- W2393338417 creator A5057523275 @default.
- W2393338417 date "1964-01-01" @default.
- W2393338417 modified "2023-09-25" @default.
- W2393338417 title "HYDROSTATIC PRESSURE CORRECTION FOR THE SEDIMENTATION COEFFICIENT AND THE MONODISPERSE s-M, [η]-MRELATIONS FOR THE SYSTEMPOLYDIMETHYLSILOXANE-BROMOCYCLOHEXANEAT θ-TEMPERATURE" @default.
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