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- W2393650557 abstract "LiNi1/3Co1/3Mn1/3O2 and Li(Ni1/3Co1/3Mn1/3)0.98Zr0.02O2 as Li-ion battery cathode materials were synthesized by high temperature solid state reaction with Ni1/3Co1/3Mn1/3(OH)2 as precursor.The results of XRD and electrochemical performance tests showed that less cation mixing and more ordered hexagonal structure were observed from the Zr-doped material.The electrochemical performance of material doping Zr was better than LiNi1/3Co1/3Mn1/3O2,though the initial charge-discharge capacities were decreased slightly,but the initial charge-discharge efficiency was 94.4%,the capacity retention rate was 99.5% after 100 cycles.The internal resistance of battery with Zr-doped material was 67.0 mΩ in final state and the capacity retention rate was 92.1% after 100 cycles at 60 ℃.The reason of the high temperature performance improved was that the reactions between Li(Ni1/3Co1/3Mn1/3)0.98Zr0.02O2 and electrolyte caused by the unstable hexagonal structure were restrained by Zr." @default.
- W2393650557 created "2016-06-24" @default.
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- W2393650557 date "2007-01-01" @default.
- W2393650557 modified "2023-09-27" @default.
- W2393650557 title "Effects of doping Zr on the performance of LiNi_(1/3)Co_(1/3)Mn_(1/3)O_2" @default.
- W2393650557 hasPublicationYear "2007" @default.
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