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- W2393846585 abstract "Catalyst Ni/ZrO2-CeO2-Al2O3 was synthesized by hydrothermal method,of which the composition was subsequently characterized using X-ray diffraction spectroscopy(XRD) and X-ray fluorescence spectroscopy(XRF).Taking Ni/ZrO2-CeO2-Al2O3 as the catalyst and wollastonite as the carbon sequestration agent,CO-supercritical water-gas shift(WGS) experiments were carried out in a high-temperature high-pressure autoclave,so as to analyze the influence of temperature and pressure on the WGS reaction,and study the feasibility of hydrogen production and carbon sequestration by WGS reaction.Results indicate that the addition of catalyst Ni/ZrO2-CeO2-Al2O3 can simultaneously raise the efficiency of both hydrogen production and mineral sequestration,respectively by an increase of 8% and 8.2% at most.For an addition of 1 g catalyst and 10 g wollastonite,the hydrogen production rate can reach 16.8%,and the CO2 mineral sequestration rate can achieve 38.1%,at an initial CO pressure of 6 MPa and a reaction temperature of 400 ℃.With existence of Ni/ZrO2-CeO2-Al2O3 catalyst in the reaction system,initial CO pressure influences more on the CO2 sequestration,while temperature impacts more on the hydrogen production." @default.
- W2393846585 created "2016-06-24" @default.
- W2393846585 creator A5026332974 @default.
- W2393846585 date "2011-01-01" @default.
- W2393846585 modified "2023-09-25" @default.
- W2393846585 title "Effect of Catalyst Ni/ZrO_2-CeO_2-Al_2O_3 on CO-Supercritical WGS Reaction for Hydrogen Production and Carbon Sequestration" @default.
- W2393846585 hasPublicationYear "2011" @default.
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