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• W2393940109 abstract "In this paper, Li3V2(PO4)3/C was synthesized using the carbon thermal reduction method. The electrochemical performance of Li3V2(PO4)3/C in a broad electrochemical window was studied. The fine structure of Li3V2(PO4)3/C after cycling in different charge and discharge ranges was investigated by X-ray powder diffraction (XRD) refinement, X-ray absorption fine structure (XAFS), X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM). The results show that the cycling stability of this material decreases with the increase of charge cut-off voltages. After cycling, the unit cell volume of Li3V2(PO4)3/C expanded irreversibly, in which the lengths of the Li(3)–O and V–O bonds became longer while those of Li(2)–O and Li(1)–O bonds became shorter. In the meantime, the amount of V5 + in the material increased and the carbon layer coated on the surface of the material was destroyed as the charge cut-off voltage was increased from 4.3 to 4.8 V. It is therefore reasonable to infer that the changes in the crystal structure of Li3V2(PO4)3/C cause the poor cycling performance of Li3V2(PO4)3/C. This result provides a research idea for improving the cyclic performance of Li3V2(PO4)3/C in the future." @default.
• W2393940109 created "2016-06-24" @default.
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• W2393940109 date "2016-08-01" @default.
• W2393940109 modified "2023-10-17" @default.
• W2393940109 title "Cycling stability of Li3V2 (PO4)3/C cathode in a broad electrochemical window" @default.
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• W2393940109 doi "https://doi.org/10.1016/j.jelechem.2016.05.020" @default.
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