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- W2394089711 abstract "The solubilities of a solid mixture of 3,5-dinitrobenzoic acid and m-nitrobenzoic acid (mixed in a ratio 1∶1 by mass) in supercritical CO2 with 3.5% mole fractions of ethanol or ethyl acetate as cosolvent have been studied at 318 K and 10.0-21.0 MPa,using a flow-type method. The solubilities of the solutes were significantly enhanced in the presence of ethanol or ethyl acetate,and the effects of different cosolvents varied for the two solutes. The effects of solute polarity,cosolvent polarity and hydrogen bonding on the solubility were investigated. The solubility data showed a satisfactory correlation with the Sovova model. The average absolute relative deviation was 8.16%,8.35%,2.40% and 2.14%,respectively." @default.
- W2394089711 created "2016-06-24" @default.
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- W2394089711 date "2010-01-01" @default.
- W2394089711 modified "2023-09-25" @default.
- W2394089711 title "The solubility of mixtures of 3,5-dinitrobenzoic acid and m-nitrobenzoic acid in supercritical-CO_2 with added cosolvents" @default.
- W2394089711 hasPublicationYear "2010" @default.
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