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- W2394266535 abstract "One monolayer containing thiol-tailed groups was formed through the covalent binding of(4,4′,4″,4) tetracarboxyl cobalt phthlocyanine(CoTcPc) on a cysteamine-modified gold electrode by using the self-assembly technique.Its electrical properties were studied,and the surface was characterized.The average surface coverage of CoTcPc was 3.7×10~(-10) mol/cm~(2),and the electron transfer rate constant(K_S) was 1.21 s~(-1).The modified gold electrode showed an excellent electrocatalytic activity for oxidation of reduced nicotinamide adenine dinucleotide(NADH) in phosphate buffer solution(pH 7.0),with an overpotential ca.300 mV which is lower than that at a bare electrode.The steady-state current increased linearly with NADH concentration in the range of 5.0×l0~(-6)～3.2×10~(-3) mol/L and the detection limit was 2.8 μmol/L.The mechanism of the oxidation of NADH catalyzed by CoTcPc modified gold electrode was discussed.The catalytic rate constant K and K~(app)_M of the modified electrode for the oxidation of NADH was determined by rotating disk electrode." @default.
- W2394266535 created "2016-06-24" @default.
- W2394266535 creator A5048225402 @default.
- W2394266535 date "2006-01-01" @default.
- W2394266535 modified "2023-09-23" @default.
- W2394266535 title "Study on the Electrochemical Catalysis of NADH by Tetra Carboxyl Cobalt(II) phthlocyanine-Cysteamine Self Assembly Au Electrode" @default.
- W2394266535 hasPublicationYear "2006" @default.
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