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- W2394310254 abstract "Two kinds of amorphous Li+ conductor, B2O3-0.7Li2O-0.7LiCl-xAl2O3-0.1V2O5,(x= 0.05 and 0.15), were studied with differential thermal analysis, conductivity measurement, X-ray diffraction and ESR spectroscopy. We find that: (1)V2O5 not only is amorphous network former, but also changes the process of crystallization;(2) For both the B2O3-Li2O-LiCl-Al2O3-V2O5 glasses and the P2O5-Li2O-LiCl-Al2O3 glasses,ionic conductivity of the tablet sample is 26 times higher than that of 60 mesh powder sample of the same material; the whole piece of glass has an obviously lower activation energy and a conductivity that is two orders higher than that of the tablet sample, so it is more suitable for ion transport; (3) Adding V2O5 less than 3.9mol% to amorphous Li+ conductor B2O3-0.7Li2O-0.7LiCl-xAl2O3 (0≤x≤0.15) does not cause electron-conductivity to increase rapidly. Further more, this makes it possible to apply the technique of ESR to study the micro structure of and electron movement in the material." @default.
- W2394310254 created "2016-06-24" @default.
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- W2394310254 date "1992-01-01" @default.
- W2394310254 modified "2023-09-27" @default.
- W2394310254 title "INVESTIGATION ON ELECTRICAL PROPERTIES AND ESR OF AMORPHOUS Li+ CONDUCTOR B2O3-0.7Li2O-0.7LiCl-xAl2O3-0.1V2O5" @default.
- W2394310254 doi "https://doi.org/10.7498/aps.41.448" @default.
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