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• W2394672153 abstract "Abstract Due to their excellent catalytic properties under mild reaction conditions, well-defined, nanosized noble metal catalysts have potential applications in the manufacture of fine chemicals, pharmaceuticals, and food additives. Ligand stabilized M n L m NCs (M: noble metal; n: number of metal atoms, n  n L m NCs. Thus, NCs can serve as model catalysts for understanding fundamental aspects of catalysis, but they also exhibit interesting properties in practical applications. M n L m NCs such as the recently investigated thiolated capped Au NCs have unique geometric structures with ultra-small size and strong quantum confinement, both of which are lacking in larger noble metal nanoparticles (>2 nm). The correlations among the catalytic performance of M n L m NCs with the size, structure, and composition of individual NCs at the atomic level can be demonstrated in realistic ambient reaction conditions, thereby contributing to the rational design of highly active catalysts with novel properties. Our current understanding of these newly emerging catalytic NCs is still in its infancy, but some studies have shown their potential for promoting new types of reactions. This review summarizes recent exciting advances in this field (since 2010), especially the catalytic properties of noble metal NCs in the presence of the ligand shell and after removing the ligand." @default.
• W2394672153 created "2016-06-24" @default.
• W2394672153 creator A5042380222 @default.
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• W2394672153 creator A5073655937 @default.
• W2394672153 creator A5082806907 @default.
• W2394672153 date "2016-09-01" @default.
• W2394672153 modified "2023-09-29" @default.
• W2394672153 title "Recent advances in the synthesis and catalytic applications of ligand-protected, atomically precise metal nanoclusters" @default.
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