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- W2394815392 abstract "Abstract A valid strategy via a gas-solid reaction for preparing Mg-based nanocomposite with controllable crystallite size and suitable for massive production is proposed. The nanocomposites consisting of well-dispersed catalytic nano-Mg 2 NiH 4 /CeH 2.73 embedded in the nano-MgH 2 matrix with crystallite sizes of all phases below 10 nm are fabricated via controlling activation temperature and hydrogen gas (H 2 ) pressure upon the amorphous Mg 80 Ce 10 Ni 10 alloy. Increasing H 2 pressure and reducing temperature are beneficial for obtaining fine hydrides, leading to lowered hydrogen desorption temperature. MgH 2 and CeH 2.73 gradually grow up with the increase of de-/re-hydrogenation cycles, while Mg 2 NiH 4 remains stable during cycling. After 15 de-/re-hydrogenation cycles, the finest nanocomposite shows remarkably reduced activation energy of dehydrogenation of 87 ± 7 kJ/mol (∼160 kJ/mol for commercial MgH 2 )." @default.
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- W2394815392 date "2016-11-01" @default.
- W2394815392 modified "2023-10-17" @default.
- W2394815392 title "Controlling nanocrystallization and hydrogen storage property of Mg-based amorphous alloy via a gas-solid reaction" @default.
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- W2394815392 doi "https://doi.org/10.1016/j.jallcom.2016.05.286" @default.
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