Matches in SemOpenAlex for { <https://semopenalex.org/work/W2395301834> ?p ?o ?g. }
- W2395301834 endingPage "4179" @default.
- W2395301834 startingPage "4169" @default.
- W2395301834 abstract "We analyze the optical, chemical, and electrical properties of chemical vapor deposition (CVD) grown hexagonal boron nitride (h-BN) using the precursor ammonia-borane ($H_3N-BH_3$) as a function of $Ar/H_2$ background pressure ($P_{TOT}$). Films grown at $P_{TOT}$ less than 2.0 Torr are uniform in thickness, highly crystalline, and consist solely of h-BN. At larger $P_{TOT}$, with constant precursor flow, the growth rate increases, but the resulting h-BN is more amorphous, disordered, and $sp^3$ bonded. We attribute these changes in h-BN grown at high pressure to incomplete thermolysis of the $H_3N-BH_3$ precursor from a passivated Cu catalyst. A similar increase in h-BN growth rate and amorphization is observed even at low $P_{TOT}$ if the $H_3N-BH_3$ partial pressure is initially greater than the background pressure $P_{TOT}$ at the beginning of growth. h-BN growth using the $H_3N-BH_3$ precursor reproducibly can give large-area, crystalline h-BN thin films, provided that the total pressure is under 2.0 Torr and the precursor flux is well-controlled." @default.
- W2395301834 created "2016-06-24" @default.
- W2395301834 creator A5007496801 @default.
- W2395301834 creator A5009810193 @default.
- W2395301834 creator A5011580189 @default.
- W2395301834 creator A5020275578 @default.
- W2395301834 creator A5021313599 @default.
- W2395301834 creator A5026750261 @default.
- W2395301834 creator A5027086751 @default.
- W2395301834 creator A5041813289 @default.
- W2395301834 creator A5051662579 @default.
- W2395301834 creator A5054163862 @default.
- W2395301834 creator A5056667874 @default.
- W2395301834 creator A5058120371 @default.
- W2395301834 creator A5058990274 @default.
- W2395301834 creator A5061768235 @default.
- W2395301834 creator A5068712471 @default.
- W2395301834 creator A5069497115 @default.
- W2395301834 creator A5071024897 @default.
- W2395301834 creator A5077655400 @default.
- W2395301834 date "2016-06-07" @default.
- W2395301834 modified "2023-10-16" @default.
- W2395301834 title "Role of Pressure in the Growth of Hexagonal Boron Nitride Thin Films from Ammonia-Borane" @default.
- W2395301834 cites W1966619335 @default.
- W2395301834 cites W1970403380 @default.
- W2395301834 cites W1971166174 @default.
- W2395301834 cites W1971454708 @default.
- W2395301834 cites W1973725704 @default.
- W2395301834 cites W1977071915 @default.
- W2395301834 cites W1981053966 @default.
- W2395301834 cites W1984190949 @default.
- W2395301834 cites W1990108593 @default.
- W2395301834 cites W1995552307 @default.
- W2395301834 cites W1999502040 @default.
- W2395301834 cites W2001780958 @default.
- W2395301834 cites W2006547129 @default.
- W2395301834 cites W2007661175 @default.
- W2395301834 cites W2012133167 @default.
- W2395301834 cites W2012651341 @default.
- W2395301834 cites W2013459581 @default.
- W2395301834 cites W2018032554 @default.
- W2395301834 cites W2018765018 @default.
- W2395301834 cites W2020708137 @default.
- W2395301834 cites W2022315563 @default.
- W2395301834 cites W2023465998 @default.
- W2395301834 cites W2032216042 @default.
- W2395301834 cites W2036201916 @default.
- W2395301834 cites W2037384058 @default.
- W2395301834 cites W2037878653 @default.
- W2395301834 cites W2040712061 @default.
- W2395301834 cites W2040808410 @default.
- W2395301834 cites W2042569746 @default.
- W2395301834 cites W2043644124 @default.
- W2395301834 cites W2043645739 @default.
- W2395301834 cites W2051946708 @default.
- W2395301834 cites W2054817900 @default.
- W2395301834 cites W2058456540 @default.
- W2395301834 cites W2061366494 @default.
- W2395301834 cites W2064689382 @default.
- W2395301834 cites W2067147697 @default.
- W2395301834 cites W2067940011 @default.
- W2395301834 cites W2071091014 @default.
- W2395301834 cites W2074751890 @default.
- W2395301834 cites W2077542293 @default.
- W2395301834 cites W2077980702 @default.
- W2395301834 cites W2083100726 @default.
- W2395301834 cites W2083839529 @default.
- W2395301834 cites W2085157307 @default.
- W2395301834 cites W2088732846 @default.
- W2395301834 cites W2090396112 @default.
- W2395301834 cites W2092188263 @default.
- W2395301834 cites W2097516828 @default.
- W2395301834 cites W2110646248 @default.
- W2395301834 cites W2114474373 @default.
- W2395301834 cites W2118225223 @default.
- W2395301834 cites W2118437047 @default.
- W2395301834 cites W2125389271 @default.
- W2395301834 cites W2129515233 @default.
- W2395301834 cites W2134791334 @default.
- W2395301834 cites W2138931463 @default.
- W2395301834 cites W2139511987 @default.
- W2395301834 cites W2145686973 @default.
- W2395301834 cites W2146724631 @default.
- W2395301834 cites W2167431156 @default.
- W2395301834 cites W2170284190 @default.
- W2395301834 cites W2170539287 @default.
- W2395301834 cites W2272078657 @default.
- W2395301834 cites W2312370353 @default.
- W2395301834 cites W2312966737 @default.
- W2395301834 cites W2313972434 @default.
- W2395301834 cites W2314722632 @default.
- W2395301834 cites W2316626137 @default.
- W2395301834 cites W2320854343 @default.
- W2395301834 cites W2323627322 @default.
- W2395301834 cites W2324846091 @default.
- W2395301834 cites W2324981682 @default.
- W2395301834 cites W2326072154 @default.
- W2395301834 cites W2326264087 @default.