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- W2395787802 abstract "Coulometry, based on Faraday`s work, was developed in the late 1930s in eastern Europe. Theoretically the most accurate of all analytical techniques, it is used for assaying chemical purity. Duursma, a Dutch oceanographer, suggested CO{sub 2}-coulometry for marine analyses in the 1950s. However, only after the modern CO{sub 2} coulometer was described by Huffman in 1977 did it become commonly used for this purpose. Currently, the method measures total dissolved carbon dioxide (CT) after gas extraction, and is approaching standard method status for sample sizes {>=}10 cm{sup 3}. The empirical results are superior to other methods, but our knowledge of the physical chemistry and parameters of the coulometric titration and titration cell is still incomplete. In this paper, manufacturing and operational criteria for the cells, the novel determination of O{sub 2} by CO{sub 2}-coulometry, and the possibility of the measurement of p(CO{sub 2}) and the C{sub T} of smaller samples (pore waters. ice cores, etc.) will be discussed." @default.
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- W2395787802 date "1996-10-01" @default.
- W2395787802 modified "2023-09-27" @default.
- W2395787802 title "The past, present, and future of CO{sub 2}-coulometry for the measurement of carbon dioxide in natural waters" @default.
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