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- W2396009664 abstract "A simple, facile, and environmentally benign intramolecular dehydrogenative coupling of various 1,2-diarylethylenes for the synthesis of phenanthrenes in excellent yield has been described. This new methodology uses ceric ammonium nitrate (CAN) as a promoter at room temperature and has been extended to intermolecular synthesis of biaryl compounds. The electron transfer from methoxyarene to cerium leads to cationic radical formation, which further proceeds to intramolecular coupling. Preliminary mechanistic investigation by EPR spectroscopy and density functional theory calculation suggested a similar view." @default.
- W2396009664 created "2016-06-24" @default.
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- W2396009664 creator A5080907756 @default.
- W2396009664 date "2016-06-17" @default.
- W2396009664 modified "2023-09-26" @default.
- W2396009664 title "Intramolecular Dehydrogenative Coupling of 2,3-Diaryl Acrylic Compounds: Access to Substituted Phenanthrenes" @default.
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- W2396009664 doi "https://doi.org/10.1021/acs.joc.6b00507" @default.
- W2396009664 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27232691" @default.
- W2396009664 hasPublicationYear "2016" @default.
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