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• W2396487154 abstract "Abstract Five molecular complexes 1a – 1e , of 4,7-phenanthroline ( 1 ) with various aromatic polycarboxylic acids such as benzene-1,3-dicarboxylic acid ( a ), pyridine-2,6-dicarboxylic acid ( b ), pyridine-2,5-dicarboxylic acid ( c ), benzene-1,2,3,4,5-pentacarboxylic acid ( d ) and 1,2,3,4,5,6-benzenehexacarboxylic acid ( e ) have been prepared and characterized by single crystal X-ray diffraction and thermogravimetric analyses. The analysis shows that all the assemblies crystallized as hydrates, except complex, 1c , formed between 1 and pyridine-2,5-dicarboxylic acid. Single crystal X-ray data reveals that the packing patterns of all the molecular complexes have been directed by strong hydrogen bonding O-H⋯O/O-H⋯N/N + -H⋯O − and weak hydrogen bonding C-H⋯O interactions. All the hydrated assemblies aggregate through the formation of cyclic networks as basic recognition pattern. Further, we observed that water molecules play significant role for production of supramolecular assemblies." @default.
• W2396487154 created "2016-06-24" @default.
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• W2396487154 date "2016-10-01" @default.
• W2396487154 modified "2023-09-24" @default.
• W2396487154 title "Supramolecular assemblies of 4,7-phenanthroline with various aromatic polycarboxylic acids" @default.
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• W2396487154 doi "https://doi.org/10.1016/j.molstruc.2016.05.051" @default.
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