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- W2396838235 abstract "Initially this paper provides a quantitative basis for the levels of acidity in protonic superacids above which individual homopolyatomic cations of non-metals and metals are capable of stable existence and below which they are unstable through disproportionation. It relates these reactions in superacids to similar behaviour of these cations in chloroaluminate melts of varying acidity or basicity. Monatomic cations of d- and f- transition metals in unusually low oxidation states, e.g. U3+, Ti2+, Sm2+ etc., are shown to be stabilized in superacids, the acidity of which has been enhanced by Lewis acids. Again, the parallel with chloroaluminate melt chemistry is demonstrated. The novel feature of this presentation is the postulate that, in acidic media, whether superacids or melts, cations are the normally expected species and that these disproportionate with increase in basicity. Finally, strategies are outlined for generation of cationic species in melts. These strategies give a more specific synthetic approach than that adopted in much past work." @default.
- W2396838235 created "2016-06-24" @default.
- W2396838235 creator A5070775967 @default.
- W2396838235 date "1988-03-22" @default.
- W2396838235 modified "2023-09-27" @default.
- W2396838235 title "ChemInform Abstract: Generation of Cationic Species in Chloroaluminate Melts: Strategies Based on Protonic Superacid Chemistry" @default.
- W2396838235 doi "https://doi.org/10.1002/chin.198812367" @default.
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