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• W2397444070 endingPage "12628" @default.
• W2397444070 startingPage "12624" @default.
• W2397444070 abstract "Abstract Turbo‐Hauser bases are very useful and highly reactive organometallic reagents in synthesis. Especially TMPMgCl ⋅ LiCl 1 (TMP=2,2,6,6‐tetramethylpiperidide) is an excellent base for converting a wide range of (hetero)aromatic substrates into highly functionalized compounds with a broad application in organic synthesis. The knowledge of its structure in solution is of essential importance to understand the extraordinary reactivity and selectivity. However, very little is known about the aggregation of this prominent reagent in solution. Herein, we present the THF‐solution structure of 1 by employing our newly elaborated DOSY NMR method based on external calibration curves (ECC) with normalized diffusion coefficients." @default.
• W2397444070 created "2016-06-24" @default.
• W2397444070 creator A5026369423 @default.
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• W2397444070 date "2016-06-17" @default.
• W2397444070 modified "2023-10-10" @default.
• W2397444070 title "Solution Structure of Turbo-Hauser Base TMPMgCl⋅LiCl in [D₈]THF" @default.
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• W2397444070 doi "https://doi.org/10.1002/chem.201601494" @default.
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• W2397444070 hasPublicationYear "2016" @default.
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