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• W2397498141 abstract "Abstract Hydrocarbon hybrid membranes of PEG/PMA/MPTMS/SiO2 and PEG/PMA/MPTMS/SiO2/GA were fabricated with various amounts of SiO2 and glutaraldehyde by sol–gel method. The composition of the hybrid membranes was examined by X-ray diffraction patterns, Fourier transform infrared (FTIR) spectra (FTIR-ATR) and proton nuclear magnetic resonance (NMR) techniques. The surface morphology of the cast membranes were analyzed by scanning electron microscopy. The conductivity values for all composites displayed a magnitude of 10−3 S cm−1, with greater improvements observed under conditions of various temperature and humidity. The proton conductivity of the composite membranes was measured at various temperatures at 50% RH using electrochemical impedance spectroscopy. In order to understand the proton conducting mechanism, the membranes were also subjected to conductivity measurement over wide RH range at 50 °C. It was observed that the hybrid membranes with glutaraldehyde additive as a crosslinking agent exhibited exceptionally high conductivity values at all RH conditions at 50 °C. The stable proton conductivity values at lower RH conditions indicate that the proton conduction mechanism is of diffusion type." @default.
• W2397498141 created "2016-06-24" @default.
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• W2397498141 date "2016-07-01" @default.
• W2397498141 modified "2023-09-23" @default.
• W2397498141 title "PEG based hybrid composite membranes and their properties for H2/O2 fuel cells" @default.
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• W2397498141 doi "https://doi.org/10.1016/j.ijhydene.2016.04.167" @default.
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