Matches in SemOpenAlex for { <https://semopenalex.org/work/W2398571102> ?p ?o ?g. }
- W2398571102 endingPage "4193" @default.
- W2398571102 startingPage "4186" @default.
- W2398571102 abstract "Nucleophilic attack by alkynyl anions on the verbenone skeleton occurs on the face opposite to that occupied by the gem-dimethyl group. The resulting alkynols react with dicobalt octacarbonyl to form tetrahedral (μ2-alkyne)Co2(CO)6 clusters in which the tricarbonylcobalt moieties are diastereotopic, and treatment with dppm tags each of these vertices with a 31P NMR label. Protonation yields a single cobalt-stabilized carbocation, 13a, in which the cobalt is situated on the side bearing the methylene bridge, thus avoiding the gem-dimethyl group, and pulls the capping phenyl substituent proximate to the hydrogen atom at C(3). All new molecules were characterized by NMR spectroscopy and by X-ray crystallography for syn-trimethylsilylethynylverbenol, 6, syn-ethynyl-verbenol, 7, and for the (2-phenylethynyl-4-methylene-6,6-dimethyl-(1S,5S)-bicyclo[3.1.1]hept-2-ene)Co2(CO)4(dppm) cluster, 12. The 2-ethynyl-4-methylene-6,6-dimethyl-bicyclo[3.1.1]hept-2-ene ligand, 15, was also prepared and characterized for the first time." @default.
- W2398571102 created "2016-06-24" @default.
- W2398571102 creator A5019214078 @default.
- W2398571102 creator A5033322606 @default.
- W2398571102 creator A5073008066 @default.
- W2398571102 creator A5073727743 @default.
- W2398571102 creator A5075866347 @default.
- W2398571102 date "2016-07-01" @default.
- W2398571102 modified "2023-10-17" @default.
- W2398571102 title "Metal-stabilized carbocations derived from monoterpenes: dicobalt hexacarbonyl complexes of alkynyl-verbenols" @default.
- W2398571102 cites W102942262 @default.
- W2398571102 cites W145420047 @default.
- W2398571102 cites W1966337010 @default.
- W2398571102 cites W1967038970 @default.
- W2398571102 cites W1973055162 @default.
- W2398571102 cites W1973510998 @default.
- W2398571102 cites W1975732821 @default.
- W2398571102 cites W1980967391 @default.
- W2398571102 cites W1983924408 @default.
- W2398571102 cites W1991858121 @default.
- W2398571102 cites W1998273904 @default.
- W2398571102 cites W1999198579 @default.
- W2398571102 cites W1999451864 @default.
- W2398571102 cites W2003471112 @default.
- W2398571102 cites W2004753549 @default.
- W2398571102 cites W2009576716 @default.
- W2398571102 cites W2025469965 @default.
- W2398571102 cites W2028011890 @default.
- W2398571102 cites W2029004352 @default.
- W2398571102 cites W2031348074 @default.
- W2398571102 cites W2032757717 @default.
- W2398571102 cites W2035591887 @default.
- W2398571102 cites W2037411764 @default.
- W2398571102 cites W2038980759 @default.
- W2398571102 cites W2041037787 @default.
- W2398571102 cites W2044568919 @default.
- W2398571102 cites W2048438618 @default.
- W2398571102 cites W2053114263 @default.
- W2398571102 cites W2058883212 @default.
- W2398571102 cites W2061446643 @default.
- W2398571102 cites W2064009603 @default.
- W2398571102 cites W2071705741 @default.
- W2398571102 cites W2087629896 @default.
- W2398571102 cites W2091393089 @default.
- W2398571102 cites W2093552525 @default.
- W2398571102 cites W2094170879 @default.
- W2398571102 cites W2095522536 @default.
- W2398571102 cites W2104420794 @default.
- W2398571102 cites W2124888253 @default.
- W2398571102 cites W2144861584 @default.
- W2398571102 cites W2148548617 @default.
- W2398571102 cites W2222904637 @default.
- W2398571102 cites W2327841955 @default.
- W2398571102 cites W2952262338 @default.
- W2398571102 cites W2952485622 @default.
- W2398571102 cites W2952929902 @default.
- W2398571102 cites W3004624452 @default.
- W2398571102 cites W3004994142 @default.
- W2398571102 cites W2124114072 @default.
- W2398571102 doi "https://doi.org/10.1016/j.tet.2016.05.044" @default.
- W2398571102 hasPublicationYear "2016" @default.
- W2398571102 type Work @default.
- W2398571102 sameAs 2398571102 @default.
- W2398571102 citedByCount "2" @default.
- W2398571102 countsByYear W23985711022016 @default.
- W2398571102 countsByYear W23985711022020 @default.
- W2398571102 crossrefType "journal-article" @default.
- W2398571102 hasAuthorship W2398571102A5019214078 @default.
- W2398571102 hasAuthorship W2398571102A5033322606 @default.
- W2398571102 hasAuthorship W2398571102A5073008066 @default.
- W2398571102 hasAuthorship W2398571102A5073727743 @default.
- W2398571102 hasAuthorship W2398571102A5075866347 @default.
- W2398571102 hasConcept C109057382 @default.
- W2398571102 hasConcept C116569031 @default.
- W2398571102 hasConcept C145148216 @default.
- W2398571102 hasConcept C155647269 @default.
- W2398571102 hasConcept C161790260 @default.
- W2398571102 hasConcept C170493617 @default.
- W2398571102 hasConcept C178790620 @default.
- W2398571102 hasConcept C178907741 @default.
- W2398571102 hasConcept C185592680 @default.
- W2398571102 hasConcept C24961977 @default.
- W2398571102 hasConcept C2777454769 @default.
- W2398571102 hasConcept C2778689049 @default.
- W2398571102 hasConcept C2779012754 @default.
- W2398571102 hasConcept C30095370 @default.
- W2398571102 hasConcept C515602321 @default.
- W2398571102 hasConcept C55493867 @default.
- W2398571102 hasConcept C66974803 @default.
- W2398571102 hasConcept C71240020 @default.
- W2398571102 hasConceptScore W2398571102C109057382 @default.
- W2398571102 hasConceptScore W2398571102C116569031 @default.
- W2398571102 hasConceptScore W2398571102C145148216 @default.
- W2398571102 hasConceptScore W2398571102C155647269 @default.
- W2398571102 hasConceptScore W2398571102C161790260 @default.
- W2398571102 hasConceptScore W2398571102C170493617 @default.
- W2398571102 hasConceptScore W2398571102C178790620 @default.
- W2398571102 hasConceptScore W2398571102C178907741 @default.