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• W2398949310 abstract "An unprecedented quaternary sulfide borate, Sm3S3BO3 (1), was obtained via a high-temperature solid-state synthesis method. It crystallizes in the triclinic space group P1̅, and its 3D structure features a 2D (Sm2S2)∞ wrinkled layer and a 1D (SmS)∞ ladderlike chain bridged by trigonal-planar (BO3)(3-) through Sm-O bonds, demonstrating the first sulfide borate without S-O and B-S bonds. Its optical energy gap is measured to be around 2.5 eV and verified by electronic structure calculation." @default.
• W2398949310 created "2016-06-24" @default.
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• W2398949310 date "2015-11-11" @default.
• W2398949310 modified "2023-10-18" @default.
• W2398949310 title "Sm₃S₃BO₃: The First Sulfide Borate without S–O and B–S Bonds" @default.
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• W2398949310 doi "https://doi.org/10.1021/acs.inorgchem.5b01930" @default.
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