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- W2399753355 abstract "Those peritectic alloys with large positive mixing enthalpy usually display metastable liquid phase separation. Here, the solidification kinetics for a model Fe50Cu50 alloy in broad cooling rate Rc range was predicted by phase-field simulations and confirmed by drop tube experiments. Near-equilibrium peritectic solidification occurs in small Rc regime below 5.62×102 K s−1. As Rc rises beyond 7.76×102 K s−1, metastable phase separation takes place and results in the formation of a dispersed structure. Afterwards, multilayer core-shell structures appear, and the layer-number varies from two-layer to six-layer with further increasing Rc. Once Rc exceeds 3.64×105 K s−1, a dispersed structure once again forms because the core-shell dynamic condition is not satisfied. Non-equilibrium peritectic solidification is induced if Rc is greater than 5.85×105 K s−1." @default.
- W2399753355 created "2016-06-24" @default.
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- W2399753355 date "2016-10-01" @default.
- W2399753355 modified "2023-10-18" @default.
- W2399753355 title "Predicting and confirming the solidification kinetics for liquid peritectic alloys with large positive mixing enthalpy" @default.
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- W2399753355 doi "https://doi.org/10.1016/j.matlet.2016.05.110" @default.
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