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- W2400081913 abstract "Batch extraction data was used to model the hybrid mechanism of chemical reaction and physical solvation involved in the perchloroethylene coal desulfurization process. Two models, pseudo-first order and second order, are presented to represent the extraction mechanism. Multiple parameter estimates have been found which minimize the model-data discrepancies. Novel methods have been devised to illustrate multiple estimates of the kinetic parameters. Ill-posedness of the kinetic modeling problem has been analyzed using the expression for extractability and the Hessian matrix of the model-data discrepancy function. In an effort to present the sensitivity of parameters to the kinetic models, a novel method called eigenvalue analysis has been developed. A comparison is also made between the second order model and the pseudo-first order model." @default.
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- W2400081913 date "1994-12-31" @default.
- W2400081913 modified "2023-09-27" @default.
- W2400081913 title "Kinetic modeling of perchloroethylene coal desulfurization process" @default.
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