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• W2400278191 abstract "A rhodium-catalyzed stepwise asymmetric 1,4- and 1,2-addition of arylboronic acids to α,β-unsaturated cyclic N-sulfonyl ketimines has been developed, providing a wide range of gem-diaryl-substituted chiral benzosulfamidates with high optical purities. C1-Symmetric chiral diene and branched chiral sulfur-olefin ligands were sequentially utilized in this double-arylation process for high stereocontrol. Further synthetic utility offers new opportunities for the facile construction of otherwise difficult to access polycyclic heterocycles." @default.
• W2400278191 created "2016-06-24" @default.
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• W2400278191 date "2016-05-17" @default.
• W2400278191 modified "2023-09-24" @default.
• W2400278191 title "Construction of Cyclic Sulfamidates Bearing Two <i>gem</i>-Diaryl Stereocenters through a Rhodium-Catalyzed Stepwise Asymmetric Arylation Protocol" @default.
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• W2400278191 doi "https://doi.org/10.1021/acs.orglett.6b01183" @default.
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