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- W2400540581 abstract "A bifunctional organic linker 4-(4-carboxyphenyl)-1,2,4-triazole (HCPT), incorporating both carboxylate and triazole groups, has been successfully used in the construction of a 2-fold interpenetrated dynamic metal-organic framework (MOF), {[Cu3(CPT)4(μ3-OH)]·NO3·7H2O·EtOH}n (1) based on a triangular Cu(II)-hydroxo cluster as secondary building unit (SBU). Upon solvation/desolvation and temperature, the crystal cell parameters of 1 could be fine-tuned. More importantly, a transformation from disordered phase to a more ordered phase after activation was observed via a single-crystal-to-single-crystal mode. Gas sorption studies reveal that the activated 1 exhibits highly selective sorption of CO2 over N2 and CH4 at room temperature." @default.
- W2400540581 created "2016-06-24" @default.
- W2400540581 creator A5028467654 @default.
- W2400540581 creator A5072862631 @default.
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- W2400540581 date "2015-05-19" @default.
- W2400540581 modified "2023-10-14" @default.
- W2400540581 title "Microporous Metal–Organic Framework Based on a Bifunctional Linker for Selective Sorption of CO<sub>2</sub> over N<sub>2</sub> and CH<sub>4</sub>" @default.
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- W2400540581 doi "https://doi.org/10.1021/acs.inorgchem.5b00561" @default.
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