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- W2400654705 abstract "A convenient and simple method for the synthesis of novel 3,4‐dihydrofuran‐annulated coumarins, 3‐(hydroxymethyl)‐2 H ‐furo[3,2‐ c ]chromen‐4(3 H )‐ones 5a , 5b , 5c , 5d , 5e , 5f , 5g , by combined Claisen rearrangement and intramolecular regioselective oxidative cyclization of 4‐ O ‐allyl coumarin intermediates 3a , 3b , 3c , 3d , 3e , 3f , 3g using inexpensive oxidizing agent m ‐CPBA is described. The reaction proceeds smoothly by tandem epoxidation/regioselective 5‐exo‐tet‐intramolecular ring opening. The structures of synthesized compounds are established on the basis of spectral data including IR, 1 H NMR, and mass and elemental analyses." @default.
- W2400654705 created "2016-06-24" @default.
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- W2400654705 date "2014-06-11" @default.
- W2400654705 modified "2023-10-05" @default.
- W2400654705 title "Combined Claisen Rearrangement and Oxidative Cyclization as a Route to Hydroxymethyl Dihydrofuran-Annulated Coumarins" @default.
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- W2400654705 doi "https://doi.org/10.1002/jhet.2069" @default.
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