FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2400705100> ?p ?o ?g. }

• W2400705100 endingPage "197" @default.
• W2400705100 startingPage "181" @default.
• W2400705100 abstract "On-surface synthesis has attracted great attention in recent years due to its promising potential for creating functional structures on surfaces. An important aspect of on-surface synthesis is the capability to arrive at covalently linked thermally stable structures that offer the possibility for application even in harsh environments outside ultra-high vacuum conditions. Additionally, covalent linking allows for fabricating conjugated structures with superior electron transport properties. Especially, the latter is of tremendous interest when considering future applications in the field of molecular electronics. Having molecular electronics applications in mind explains the need for decoupling of the electronic structure of the molecular network from the underlying support surface. Thus, it is highly interesting to transfer on-surface synthesis strategies from metallic to insulating surfaces. Albeit, insulating surfaces pose several challenges for on-surface synthesis. First, many prototypical insulating support materials interact only weakly with organic molecules. This weak binding frequently results in molecule desorption rather than reaction activation when thermally initiating the reaction. Second, it is known that metals act as catalyst for several reactions that have been performed successfully on metallic surfaces. A simple transfer of these reactions to insulating surfaces in the absence of metal atoms is, therefore, questionable and requires different reaction pathways to be considered. In this chapter, we review the current state-of-the-art in on-surface synthesis on electrically insulating substrates carried out in ultra-high vacuum. Proof-of-principle reactions are discussed with an emphasis on strategies to overcome challenges related to the weak molecule-surface binding often present on insulating surfaces, e.g., by means of photochemical activation. Site-specific and sequential reactions are presented as a promising way for enhancing control and structural complexity of on-surface synthesis on insulating support materials. Finally, the influence of the substrate is shown to induce directionality in on-surface synthesis by favoring specific surface directions." @default.
• W2400705100 created "2016-06-24" @default.
• W2400705100 creator A5029829174 @default.
• W2400705100 creator A5055371968 @default.
• W2400705100 creator A5077997933 @default.
• W2400705100 date "2016-01-01" @default.
• W2400705100 modified "2023-10-16" @default.
• W2400705100 title "On-Surfaces Synthesis on Insulating Substrates" @default.
• W2400705100 cites W1963973149 @default.
• W2400705100 cites W1964084591 @default.
• W2400705100 cites W1968103630 @default.
• W2400705100 cites W1968927817 @default.
• W2400705100 cites W1970728830 @default.
• W2400705100 cites W2004976864 @default.
• W2400705100 cites W2005382947 @default.
• W2400705100 cites W2018371249 @default.
• W2400705100 cites W2023151394 @default.
• W2400705100 cites W2025347444 @default.
• W2400705100 cites W2028253542 @default.
• W2400705100 cites W2037280767 @default.
• W2400705100 cites W2038140186 @default.
• W2400705100 cites W2041367980 @default.
• W2400705100 cites W2042260160 @default.
• W2400705100 cites W2044492970 @default.
• W2400705100 cites W2046032184 @default.
• W2400705100 cites W2049557082 @default.
• W2400705100 cites W2057977780 @default.
• W2400705100 cites W2059025851 @default.
• W2400705100 cites W2065565022 @default.
• W2400705100 cites W2071094479 @default.
• W2400705100 cites W2084065348 @default.
• W2400705100 cites W2090448025 @default.
• W2400705100 cites W2138964626 @default.
• W2400705100 cites W2150251688 @default.
• W2400705100 cites W2166546391 @default.
• W2400705100 cites W2186636421 @default.
• W2400705100 cites W2316605725 @default.
• W2400705100 cites W2323528214 @default.
• W2400705100 doi "https://doi.org/10.1007/978-3-319-26600-8_9" @default.
• W2400705100 hasPublicationYear "2016" @default.
• W2400705100 type Work @default.
• W2400705100 sameAs 2400705100 @default.
• W2400705100 citedByCount "3" @default.
• W2400705100 countsByYear W24007051002018 @default.
• W2400705100 countsByYear W24007051002019 @default.
• W2400705100 crossrefType "book-chapter" @default.
• W2400705100 hasAuthorship W2400705100A5029829174 @default.
• W2400705100 hasAuthorship W2400705100A5055371968 @default.
• W2400705100 hasAuthorship W2400705100A5077997933 @default.
• W2400705100 hasConcept C123057669 @default.
• W2400705100 hasConcept C127413603 @default.
• W2400705100 hasConcept C133731056 @default.
• W2400705100 hasConcept C150394285 @default.
• W2400705100 hasConcept C159467904 @default.
• W2400705100 hasConcept C162711632 @default.
• W2400705100 hasConcept C171250308 @default.
• W2400705100 hasConcept C178790620 @default.
• W2400705100 hasConcept C180577832 @default.
• W2400705100 hasConcept C185592680 @default.
• W2400705100 hasConcept C191897082 @default.
• W2400705100 hasConcept C192562407 @default.
• W2400705100 hasConcept C205606062 @default.
• W2400705100 hasConcept C32909587 @default.
• W2400705100 hasConcept C544153396 @default.
• W2400705100 hasConceptScore W2400705100C123057669 @default.
• W2400705100 hasConceptScore W2400705100C127413603 @default.
• W2400705100 hasConceptScore W2400705100C133731056 @default.
• W2400705100 hasConceptScore W2400705100C150394285 @default.
• W2400705100 hasConceptScore W2400705100C159467904 @default.
• W2400705100 hasConceptScore W2400705100C162711632 @default.
• W2400705100 hasConceptScore W2400705100C171250308 @default.
• W2400705100 hasConceptScore W2400705100C178790620 @default.
• W2400705100 hasConceptScore W2400705100C180577832 @default.
• W2400705100 hasConceptScore W2400705100C185592680 @default.
• W2400705100 hasConceptScore W2400705100C191897082 @default.
• W2400705100 hasConceptScore W2400705100C192562407 @default.
• W2400705100 hasConceptScore W2400705100C205606062 @default.
• W2400705100 hasConceptScore W2400705100C32909587 @default.
• W2400705100 hasConceptScore W2400705100C544153396 @default.
• W2400705100 hasLocation W24007051001 @default.
• W2400705100 hasOpenAccess W2400705100 @default.
• W2400705100 hasPrimaryLocation W24007051001 @default.
• W2400705100 hasRelatedWork W1548038933 @default.
• W2400705100 hasRelatedWork W1968523096 @default.
• W2400705100 hasRelatedWork W1973808345 @default.
• W2400705100 hasRelatedWork W2052851759 @default.
• W2400705100 hasRelatedWork W2099662887 @default.
• W2400705100 hasRelatedWork W2125892451 @default.
• W2400705100 hasRelatedWork W2989968602 @default.
• W2400705100 hasRelatedWork W3161173879 @default.
• W2400705100 hasRelatedWork W3173589548 @default.
• W2400705100 hasRelatedWork W4230726097 @default.
• W2400705100 isParatext "false" @default.
• W2400705100 isRetracted "false" @default.
• W2400705100 magId "2400705100" @default.
• W2400705100 workType "book-chapter" @default.