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- W2400732010 abstract "ABSTRACTConvenient synthetic routes to the compounds WNBr3 and WNBr2(bpy) are described using WBr4 as the starting material. One-pot syntheses using W(CO)6, Br2, (CH3)3SiN3, and 2,2′-bipyridine as inexpensive and readily available starting materials are also described. These one-pot syntheses produce analytically pure compounds in gram quantities with high yields under mild conditions. Use of (CH3)3SiN3 as a nitride source is preferable to that of unstable and explosive IN3 which has been utilized in previous preparations of tungsten-nitrido compounds." @default.
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- W2400732010 date "2016-05-24" @default.
- W2400732010 modified "2023-09-24" @default.
- W2400732010 title "Improved synthetic routes to tungsten-nitrido compounds" @default.
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- W2400732010 doi "https://doi.org/10.1080/15533174.2015.1137315" @default.
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