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- W240124961 abstract "The boronic acid group in the title compound, C 11 H 11 BN 2 O 3 , adopts a syn–anti conformation and is almost coplanar with the aromatic rings , making a dihedralangle of 3.8 (2)°. In the crystal, adjacent molecules are linked via pairs of O—H...O interactions, forming centrosymmetric dimers with an R 2 2 (8) motif, which have recently been shown to be energetically very favorable (Durka et al. , 2012, 2014). The hydroxy groups in an anti conformation are engaged in lateral hydrogen-bonding interactions with N atoms from neighbouring molecules, leading to the formation of chains along [001]. O...B [3.136 (2) Å] and C(π)...B [3.393 (2) Å] stacking interactions in turn link parallel chains of centrosymmetric dimers into layers parallel to (010)." @default.
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- W240124961 date "2014-11-15" @default.
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- W240124961 title "Crystal structure of (2-benzyloxypyrimidin-5-yl)boronic acid" @default.
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- W240124961 doi "https://doi.org/10.1107/s1600536814024519" @default.
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