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- W2401472576 abstract "The vibrational dynamics of HOCl and HOBr between bending and OCl/OBr stretching coordinates with anharmonicity and Fermi coupling is studied with the classical dynamical potential approach. The quantal vibrational dynamics is mostly mapped out by the classical nonlinear variables such as fixed points, except for the state energies, which are quantized. This approach is global in the sense that the focus is on a set of levels instead of individual ones. The dynamics of HOBr is demonstrated to be less complicated. The localized modes along the OCl/OBr stretching coordinates are also shown to have O–Br bonds more prone to dissociation." @default.
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- W2401472576 date "2010-01-01" @default.
- W2401472576 modified "2023-10-17" @default.
- W2401472576 title "Global dynamical analysis of vibrational manifolds of HOCl and HOBr under anharmonicity and Fermi resonance: the dynamical potential approach" @default.
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- W2401472576 doi "https://doi.org/10.1088/1674-1056/19/1/010509" @default.
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